Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications

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Name Reactions A Collection of Detailed Mechanisms and Synthetic Applications

Bucherer carbazole synthesis. Bucherer reaction. Burke horonates.


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Chan alkyne reduction. Claisen condensation. Clemrnensen reduction. Darzens condensation. DessMartin periodinane oxidation.

Name Reactions: A Collection of Detailed Mechanisms and Synthetic Applications Fifth Edition

Dienonephenol rearrangement. Doebnervon Miller reaction. EschenmoserTanabe fragmentation. Favorskii rearrangement. Ferrier carbocyclization. Fischer indole synthesis. FriedelCrafts reaction. Fries rearrangement. Gabriel synthesis. GattermannKoch reaction. GombergBachmann reaction.

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Grob fragmentation. Hantzsch dihydropyridine synthesis. Hegedus indole synthesis. Hiyama crosscoupling reaction. HornerWadsworthEmmons reaction. J acobsenKatsuki epoxidation. JuliaKocienski olefination. Nef reaction 3 NozakiHiyamaKishi reaction. Passerini reaction. Petasis reagent. PictetGams isoquinoline synthesis.

Pinner reaction 43 8. PomeranzFritsch reaction. Pschorr cyclization.

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Reformatsky reaction. Reissert indole synthesis.

Name Reactions: A Collection Of Detailed Mechanisms And Synthetic Applications

Robinson annulation. Rosenmund reduction. Saegusa oxidation. Schiemann reaction. Shapiro reaction. Sharpless asymmetric epoxidation. In addition to the use of the names of chemists, we also have groundbreaking reactions that come to be known by abbreviations of a descriptive name, such as "RCM" ring-closing metathesis or INOC intramolecular nitrile oxide cyclization.

Name Reactions: A Collection of Detailed Mechanisms and Synthetic - Jie Jack Li - Google книги

We seldom use the name of the chemist who developed RCM Robert Grubbs to refer to the reaction, but his contribution is instead acknowledged by applying his name to the ruthenium-catalysts used. Thus, we speak of the "Grubbs catalyst" or "2nd generation Grubbs catalyst". Besides names such as "RCM", some frequently used reactions are named for structural features of the precursor or product. Examples include the "aldol reaction" "aldol" is an abbreviation of a compound that contains both aldehyde and alcohol functionalities or the "pinacol rearrangement".

As mentioned above, name reactions are used to refer to groundbreaking reactions or the associated mechanisms or principles that are worthwhile knowing and keeping straight. Just as physicians must learn the names of organs and geologists the names of minerals, chemists or students of chemistry use name reactions as a way to organize their knowledge and communicate about chemical transformations. In laboratory discussions, people very often use name reactions to refer to experiments they are running or the chemical problems they are investigating.

The name reaction is a type of shorthand that avoids the need to give a lengthier explanation of the features of a particular transformation of interest. Mentioning the name reaction allows a knowledgeable listener to bring to mind the possible substrates, reaction conditions, or mechanistic details. Everyone in the field is expected to know a basic set of name reactions by heart, and this makes discussions less time-consuming. In this way, name reactions have become part of the shared vocabulary of organic synthesis chemists.

Such recognition can signal that a listener or job candidate has command of a particular area of chemistry. This means that he or she would be capable of understanding details of the synthetic routes in the work described, and could possibly develop alternatives. Site Search any all words.